Yes - Skype does attempt to use the technique in the article, but it's far more sophisticated than that...
Skype was written by a bunch of the programmers from Kazaa, and the Skype network is essentially P2P; people who connect to the Skype network with especially good connections may become supernodes and will act as data relays for nodes having problems with other connection methods.
As an interesting aside, that's also why Skype claimed Windows Update caused their last major outage - they claim there was a bug that caused the P2P network self-healing code to work slowly, a larger-than-normal number of computers rebooted at the same time after patching and the P2P network took two days to recover from the "critical disruption".
Skype was written by a bunch of the programmers from Kazaa, and the Skype network is essentially P2P; people who connect to the Skype network with especially good connections may become supernodes and will act as data relays for nodes having problems with other connection methods.
http://en.wikipedia.org/wiki/Skype_Protocol has a fairly detailed description, for those who might be interested.